Liv looked like a sultry superstar for her appearance on The Late Show last night. And she had an outfit change to boot. So we get double Liv! One look was a lace Alexander McQueen that needs no introduction and the other is a pared-down navy silk dress and super-slick black leather jacket. She wore black McQueen heels with both and kept her coveted lips [1] bright and plump.

[1]
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Alexander McQueen Lace-Inset Dress [1]Lace-Inset Dress [1] by Alexander McQueen [1] $2,450.00 $1,593.00 at Neiman Marcus [1]
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Lauren Ralph Lauren Elantra Jacket - Petite's [1]Elantra Jacket - Petite's [1] by Lauren Ralph Lauren [1] $419.30 at Bloomingdale's [1]
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Jenni Kayne U Neck Dress in Navy/Black [1]U Neck Dress in Navy/Black [1] by Jenni Kayne [1] $575.00 $288.00 at Revolve Clothing [1]
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Alexander McQueen Satin square toe pumps [1]Satin square toe pumps [1] by Alexander McQueen [1] $595.00 $297.50 at Net-A-Porter [1]
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Sterling Silver Rhodium Cubic Zirconia Star Dangle Earrings [1]Sterling Silver Rhodium Cubic Zirconia Star Dangle Earrings [1] $24.99 at Target [1]
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Bcatalina Red Paris [1]Bcatalina Red Paris [1] by Steve Madden [1] $48.00 $29.99
Source [2]