For her latest front-row London Fashion Week look, Olivia Palermo went extra bold in an emerald-green blazer, yellow skinny jeans, and a two-tone Anya Hindmarch leather tote at the designer's Spring 2013 show. It's clear she's mastered the art of unexpected color pairings, as just hours earlier she showcased this equally amazing burnt orange and burgundy ensemble. Olivia's gray deep-v sweater and tortoise Ray-Bans balanced her bold separates, while her colorblock pumps and sparkling accessories injected the perfect amount of glamour. Style a green blazer with yellow denim and colorful pumps to channel Olivia's Fall-perfect duo for your next dinner date.