Transformation: Anne Hathaway
When it comes to lipstick, Anne Hathaway is a prodigy. "My first play at the stuff was in my mother's bathroom," she has said. "I wanted big lips, so I took her red lipstick and proceeded to run it all over my face. I was five." The 25-year-old Get Smart star has remained a fan of the classic lippy, drawing comparisons to Hollywood legends.